一定温度下的难溶电解质AmBn在水溶液中达到溶解平衡时。已知下表数据
| 物质 |
Fe(OH)2 |
Cu(OH)2 |
Fe(OH)3 |
| Ksp/25℃ |
8.0×10-16 |
2.2×10-20 |
4.0×10-38 |
| 完全沉淀时的PH值范围 |
≥9.6 |
≥6.4 |
3~4 |
对含等物质的量CuSO4、FeSO4、Fe2(SO4)3的混合溶液的说法,不科学的是
A.向该混合溶液中逐滴加入NaOH溶液,最先看到红褐色沉淀
B.该溶液中c(SO42-):{c(Cu2+)+c(Fe2+)+c(Fe3+)}>5:4
C.向该溶液中加入适量氯水,并调节pH值到3~4后过滤,得到纯净的CuSO4溶液
D.向该溶液中加少量铁粉即能观察到红色固体析出
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