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题文

【改编】900℃时,向1.0L恒容密闭容器中充入0.40mol乙苯,发生反应:
。经一段时间后达到平衡。反应过程中测定的部分数据见下表:

时间/min
0
10
20
30
40
n(乙苯)/mol
0.40
0.30
0.24
n2
n3
n(苯乙烯)/mol
0.00
0.10
n1
0.20
0.20

下列说法正确的是
A.反应在前10 min的平均速率为v(H2)=0.01mol·L-1·min-1
B.保持其他条件不变,升高温度,平衡时,c(H2)=0.22mol·L-1,则a<0
C.保持其他条件不变,压缩容器的体积为原来的一半,则乙苯的转化率大于50.0%
D.相同温度下,起始时向容器中充入0.10mol乙苯、0.10mol苯乙烯和0.20molH2,达到平衡前v(正)>v(逆)

科目 化学   题型 选择题   难度 较难
知识点: 探究温度、压强对化学平衡的影响
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