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已知K2Cr2O7溶液中存在如下平衡:Cr2O72-(橙色)+ H2O2H+ 2CrO42-(黄色)。
①向2mL 0.1mol·L  K2Cr2O7溶液中滴入3滴6mol/L NaOH溶液,溶液由橙色变为黄色;向所得溶液中再滴入5滴浓H2SO4,溶液由黄色变为橙色;
②向酸化K2Cr2O7溶液中滴入适量Na2SO3溶液,溶液由橙色变为绿色:
Cr2O72- + 8H+ 3SO32=2Cr3+(绿色) + 3SO42+ 4H2O
下列分析正确的是

A.CrO42和S2在酸性溶液中可大量共存
B.实验②说明氧化性:Cr2O72->SO42
C.稀释K2Cr2O7溶液时,溶液中各离子浓度均减小
D.实验①和②均能证明K2Cr2O7溶液中存在上述平衡
科目 化学   题型 选择题   难度 较难
知识点: 反应热的大小比较
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