已知K2Cr2O7溶液中存在如下平衡:Cr2O72-(橙色)+ H2O
2H++ 2CrO42-(黄色)。
①向2mL 0.1mol·L K2Cr2O7溶液中滴入3滴6mol/L NaOH溶液,溶液由橙色变为黄色;向所得溶液中再滴入5滴浓H2SO4,溶液由黄色变为橙色;
②向酸化K2Cr2O7溶液中滴入适量Na2SO3溶液,溶液由橙色变为绿色:
Cr2O72- + 8H++ 3SO32-=2Cr3+(绿色) + 3SO42-+ 4H2O
下列分析正确的是
| A.CrO42-和S2-在酸性溶液中可大量共存 |
| B.实验②说明氧化性:Cr2O72->SO42- |
| C.稀释K2Cr2O7溶液时,溶液中各离子浓度均减小 |
| D.实验①和②均能证明K2Cr2O7溶液中存在上述平衡 |
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